- Sandwich Shop Restaurants, Orrville
- Savings & Loan Associations, Orrville
- Savings Banks, Orrville
- Sawdust & Shavings, Orrville
- Scaffolding & Aerial Lifts, Orrville
- Search & Rescue, Orrville
- Secondary Schools, Orrville
- Security Brokers & Dealers, Orrville
- Semiconductors & Equipment, Orrville
- Service Establishment Supplies & Equipment, Orrville
- Sewer & Drain Cleaning & Repair, Orrville - Drain Cleaner & Installation Services
- Sewing & Yarn Stores & Supplies, Orrville
- Shoe Repair & Shoeshine Parlors, Orrville
- Shoe Repair Shops, Orrville
- Shopping & Shopping Services, Orrville
- Siding Contractors, Orrville - Vinyl Siding, Wood, Metal & Aluminum Siding Contractors - Installation & Repair
- Signs, Orrville
- Snacks & Desserts, Orrville
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- Social Services & Welfare, Orrville
- Sod & Sodding Service, Orrville
- Soul Food Restaurants, Orrville
- Special Interest Schools Or Instruction, Orrville
- Specialty Animal Services, Orrville
- Specialty Stores, Orrville
- Sporting Goods Stores, Orrville
- Sportswear Clothing Stores, Orrville - Sports Clothes
- Staffing & Support Services, Orrville
- State Government, Orrville
- Steel & Metal Goods, Orrville - Steel Distributors
- Steel Manufacturers, Orrville
- Steel Mills & Blast Furnaces, Orrville
- Stocks & Bond Brokers, Orrville
- Stone, Orrville
- Stoves & Furnace Equipment, Orrville - Fittings & Repair Parts
- Swimming Pool, Sauna & Spa Contractors, Orrville
- Swimming Pools Contractors, Orrville - Install Inground - Above Ground Pools
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